Exciton Lifetime Paradoxically Enhanced by Dissipation and Decoherence - Toward Efficient Energy Conversion of Solar Cell

Energy dissipation and decoherence are at first glance harmful to acquiring long exciton lifetime desired for efficient photovoltaics. In the presence of both optically forbidden (namely, dark) and allowed (bright) excitons, however, they can be instrumental as suggested in photosynthesis. By simulating quantum dynamics of exciton relaxations, we show that the optimized decoherence that imposes a quantum-to-classical crossover with the dissipation realizes a dramatically longer lifetime. In an example of carbon nanotube, the exciton lifetime increases by nearly two orders of magnitude when the crossover triggers stable high population in the dark exciton.

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