Abstract
We aim to show the importance of non-elastic excitation and deexcitation processes in collisions with the principal quantum number for helium-rich white dwarf atmospheres. We compare the efficiencies of these processes with those of the known non-elastic electron- atom processes in the atmospheres of some DB white dwarfs. We show that in significant parts of the considered atmospheres, which contain weakly ionized layers (the ionization degree ), the influence of the studied atom-Rydberg atom processes on excited helium atom populations is dominant or at least comparable to the influence of the concurrent electron--atom processes.
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