Evidence for very strong electron-phonon coupling in YBa_{2}Cu_{3}O_{6}

From the observed oxygen-isotope shift of the mid-infrared two-magnon absorption peak of YBa$_{2}$Cu$_{3}$O$_{6}$, we evaluate the oxygen-isotope effect on the in-plane antiferromagnetic exchange energy $J$. The exchange energy $J$ in YBa$_{2}$Cu$_{3}$O$_{6}$ is found to decrease by about 0.9% upon replacing $^{16}$O by $^{18}$O, which is slightly larger than that (0.6%) in La$_{2}$CuO$_{4}$. From the oxygen-isotope effects, we determine the lower limit of the polaron binding energy, which is about 1.7 eV for YBa$_{2}$Cu$_{3}$O$_{6}$ and 1.5 eV for La$_{2}$CuO$_{4}$, in quantitative agreement with angle-resolved photoemission data, optical conductivity data, and the parameter-free theoretical estimate. The large polaron binding energies in the insulating parent compounds suggest that electron-phonon coupling should also be strong in doped superconducting cuprates and may play an essential role in high-temperature superconductivity.

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