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Empirical properties of Very Massive Stars

In this contribution we present the properties of the most massive stars known by the end of 2013. We start with a summary of historical claims for stars with masses in excess of several hundreds, even thousands of solar masses. We then describe how we determine masses for single stars. We focus on the estimates of luminosities and on the related uncertainties. We also highlight the limitations of evolutionary models used to convert luminosities into masses. The most luminous single stars in the Galaxy and the Magellanic Clouds are subsequently presented. The uncertainties on their mass determinations are described. Finally, we present binary stars. After recalling some basics of binary analysis, we present the most massive binary systems and the estimates of their dynamical masses.