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Emergence of superconductivity in doped H$_2$O ice at high pressure

We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors superconducting at ambient pressure. Following this idea, we study H$_2$O, one of the most abundant and well-studied substances, we identify nitrogen as the most likely and promising substitution/dopant. We show that for realistic levels of doping of a few percent, the phase X of ice becomes superconducting with a critical temperature of about 60 K at 150GPa. In view of the vast number of hydrides that are strongly covalent bonded, but that remain insulating until rather large pressures, our results open a series of new possibilities in the quest for novel high-temperature superconductors.

preprint2016arXivOpen access

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