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Paper detail

Electron paramagnetic resonance study of ErSc2NC80

We present an electron paramagnetic resonance (EPR) study of ErSc2N@C80 fullerene in which there are two Er3+ sites corresponding to two different configurations of the ErSc2N cluster inside the C80 cage. For each configuration, the EPR spectrum is characterized by a strong anisotropy of the g factors (gx,y = 2.9, gz = 13.0 and gx,y = 5.3, gz = 10.9). Illumination within the cage absorption range (<600 nm) induces a rearrangement of the ErSc2N cluster inside the cage. We follow the temporal dependence of this rearrangement phenomenologically under various conditions.

preprint2010arXivOpen access
Rizvi RahmanArchana TiwariGeraldine DantelleJohn J. L. MortonKyriakos PorfyrakisArzhang ArdavanKlaus-Peter DinseG. Andrew D. Briggs
cond-mat.otherphysics.chem-ph
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Rizvi RahmanArchana TiwariGeraldine DantelleJohn J. L. MortonKyriakos PorfyrakisArzhang ArdavanKlaus-Peter DinseG. Andrew D. Briggs

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