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Electron Paramagnetic Resonance of Mn in Bi$_2$Se$_3$ Topological Insulator

Electron paramagnetic resonance was used to investigate Mn impurity in Bi$_2$Se$_3$ topological insulator grown by the vertical Bridgman method. Mn in high-spin S = 5/2, Mn$^2$$^+$ configuration, was detected regardless of the conductivity type of the host material. This means that Mn$^2$$^+$(d$^5$) energy level is located within the valence band, and Mn$^1$$^+$(d$^6$) energy level is outside the energy gap of Bi$_2$Se$_3$. The electron paramagnetic resonance spectrum of Mn$^2$$^+$ in Bi$_2$Se$_3$ is characterized by the isotropic g-factor |g| = 1.91 and large axial parameter D = -4.20 GHz x h. This corresponds to the zero-field splitting of the Kramers doublets equal to 8.4 GHz x h and 16.8 GHz x h, respectively, which is comparable to the Zeeman splitting for the X-band. Mn in Bi$_2$Se$_3$ acts as an acceptor, effectively reducing native-high electron concentration, compensating selenium vacancies, and resulting in p-type conductivity.