Electron-lattice instabilities suppress cuprate-like electronic structures in SrFeO3_3/SrTiO3_3 superlattices

preprint2009arXivOpen access

Abstract

Using {\it ab initio} density functional theory we explore the behavior of thin layers of metallic d4d^4 SrFeO3_3 confined between the d0d^0 dielectric SrTiO3_3 in a superlattice geometry. We find the presence of insulating SrTiO3_3 spacer layers strongly affects the electronic properties of SrFeO3_3: For single SrFeO3_3 layers constrained to their bulk cubic structure, the Fermi surface is two-dimensional, nested and resembles the hole-doped superconducting cuprates. A Jahn-Teller instability couples to an octahedral tilt mode, however, to remove this degeneracy resulting in insulating superlattices.

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