Electrocaloric effect in KH2_2PO4_4 family crystals

preprint2015arXivOpen access

Abstract

The proton ordering model for the KH2_{2}PO4_{4} type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we calculate the crystal polarization and explore the electrocaloric effect. Smearing of the ferroelectric phase transition by a longitudinal electric field is described. A good agreement with experiment is obtained.

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