Dynamical Decoupling of Spin-Clusters using Solid State NMR

In this work we experimentally study the efficiency of various dynamical decoupling sequences for suppressing decoherence of single as well as multiple quantum coherences on large spin-clusters. The system involves crystallites of a powdered sample containing a large number of molecular protons interacting via long-range dipole-dipole interaction. The multiple quantum coherences are prepared by progressively creating correlations in the spin lattice using standard pulse sequences implementing two-quantum average Hamiltonian. The spin system is then subjected to various dynamical decoupling sequences, followed by conversion into observable single quantum coherence by using time-reversal sequence. The experiments reveal superior performance of the recently introduced RUDD sequences in suppressing the decoherence.

No reviews yet.

No comments yet.