Droplet absorption and spreading into thin layers of polymer hydrogels

From biological tissues to layers of paint, macroscopic non-porous materials with the capacity to swell when brought in contact with an appropriate solvent are ubiquitous. Here, we study experimentally and theoretically one of the conceptually simplest of such systems, the swelling of a thin hydrogel layer by a single water drop. Using a bespoke experimental setup, we observe fast absorption leading to a radially spreading axisymmetric blister. Employing a linear poroelastic framework and thin-layer scalings, we develop a non-linear one-dimensional diffusion equation for the evolution of the blister height profile, which agrees well with experimental observations.

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