Dissociative recombination and rotational transitions of D2+_2^+ in collisions with slow electrons

preprint2022arXivOpen access

Abstract

Rate coefficients for dissociative recombination and state-to-state rotational transitions of the D2+_{2}^{+} ion induced by collisions with very low-energy electrons have been reported following our previous studies on HD+^{+} and H2+_{2}^{+} [9,10]. The same molecular structure data sets, excitations (Ni+→N_{i}^{+} \rightarrow Nf+=Ni++2N_{f}^{+}=N_{i}^{+}+2 for Ni+=0N_{i}^{+}=0 to 1010) and de-excitations (Ni+N_{i}^{+} →\rightarrow Nf+=Ni+−2N_{f}^{+}=N_{i}^{+}-2, for Ni+=2N_{i}^{+}=2 to 1010) were used for collision energies ranging from 0.010.01 meV to 0.30.3 eV. Isotopic effects for dissociative recombination and rotational transitions of the vibrationally relaxed targets are presented.

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