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Detailed Chemical Abundances of Four Stars in the Unusual Globular Cluster, Palomar 1

Detailed chemical abundances for twenty one elements are presented for four red giants in the anomalous outer halo globular cluster Palomar 1 ($R_{\rm{GC}} = 17.2$ kpc, $Z=3.6$ kpc) using high-resolution (R=36000) spectra from the High Dispersion Spectrograph (HDS) on the Subaru Telescope. Pal 1 has long been considered unusual because of its low surface brightness, sparse red giant branch, young age, and its possible association with two extragalactic streams of stars---this paper shows that its chemistry further confirms its unusual nature. The mean metallicity of the four stars, $[\rm{Fe/H}] = -0.60 \pm 0.01$, is high for a globular cluster so far from the Galactic center, but is low for a typical open cluster. The [$α$/Fe] ratios, though in agreement with the Galactic stars within the $1σ$ errors, agree best with the lower values in dwarf galaxies. No signs of the Na/O anticorrelation are detected in Pal 1, though Na appears to be marginally high in all four stars. Pal 1's neutron capture elements are also unusual: its high [Ba/Y] ratio agrees best with dwarf galaxies, implying an excess of second-peak over first-peak s-process elements, while its [Eu/$α$] and [Ba/Eu] ratios show that Pal 1's contributions from the r-process must have differed in some way from normal Galactic stars. Therefore, Pal 1 is chemically unusual, as well in its other properties. Pal 1 shares some of its unusual abundance characteristics with the young clusters associated with the Sagittarius dwarf galaxy remnant and the intermediate-age LMC clusters, and could be chemically associated with the Canis Majoris overdensity; however it does not seem to be similar to the Monoceros/Galactic Anticenter Stellar Stream.