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Critical points and symmetries of a free energy function for biaxial nematic liquid crystals

We describe a general model for the free energy function for a homogeneous medium of mutually interacting molecules, based on the formalism for a biaxial nematic liquid crystal set out by Katriel {\em et al.} (1986) in an influential paper in {\em Liquid Crystals} {\bf 1} and subsequently called the KKLS formalism. The free energy is expressed as the sum of an entropy term and an interaction (Hamiltonian) term. Using the language of group representation theory we identify the order parameters as averaged components of a linear transformation, and characterise the full symmetry group of the entropy term in the liquid crystal context as a wreath product $SO(3)\wr Z_2$. The symmetry-breaking role of the Hamiltonian, pointed out by Katriel {\em et al.}, is here made explicit in terms of centre manifold reduction at bifurcation from isotropy. We use tools and methods of equivariant singularity theory to reduce the bifurcation study to that of a $D_3\,$-invariant function on ${\bf R}^2$, ubiquitous in liquid crystal theory, and to describe the 'universal' bifurcation geometry in terms of the superposition of a familiar swallowtail controlling uniaxial equilibria and another less familiar surface controlling biaxial equilibria. In principle this provides a template for {\em all} nematic liquid crystal phase transitions close to isotropy, although further work is needed to identify the absolute minima that are the critical points representing stable phases.