Correlation energy of two electrons in the high-density limit

preprint2010arXivOpen access

Abstract

We consider the high-density-limit correlation energy $\Ec$ in D≥2D \ge 2 dimensions for the 1S^1S ground states of three two-electron systems: helium (in which the electrons move in a Coulombic field), spherium (in which they move on the surface of a sphere), and hookium (in which they move in a quadratic potential). We find that the $\Ec$ values are strikingly similar, depending strongly on DD but only weakly on the external potential. We conjecture that, for large DD, the limiting correlation energy $\Ec \sim -δ^2/8$ in any confining external potential, where δ=1/(D−1)δ= 1/(D-1).

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