Conventional type-II superconductivity in locally non-centrosymmetric LaRh2_2As2_2 single crystals

preprint2022arXivOpen access

Abstract

We report on the observation of superconductivity in LaRh2_2As2_2, which is the analogue without ff-electrons of the heavy-fermion system with two superconducting phases CeRh2_2As2_2. A zero-resistivity transition, a specific-heat jump and a drop in magnetic ac susceptibility consistently point to a superconducting transition at a transition temperature of Tc=0.28T_c = 0.28\,K. The magnetic field-temperature superconducting phase diagrams determined from field-dependent ac-susceptibility measurements reveal small upper critical fields μ0Hc2≈12μ_{\mathrm{0}}H_{c2} \approx 12\,mT for H∥abH\parallel ab and μ0Hc2≈9μ_{\mathrm{0}}H_{c2} \approx 9\,mT for H∥cH\parallel c. The observed Hc2H_{c2} is larger than the estimated thermodynamic critical field HcH_c derived from the heat-capacity data, suggesting that LaRh2_2As2s_2 is a type-II superconductor with Ginzburg-Landau parameters κGLab≈1.9κ^{ab}_{GL} \approx 1.9 and κGLc≈2.7κ^{c}_{GL}\approx 2.7. The microscopic Eliashberg theory indicates superconductivity to be in the weak-coupling regime with an electron-phonon coupling constant λe−ph≈0.4λ_{e-ph} \approx 0.4. Despite a similar TcT_c and the same crystal structure as the Ce compound, LaRh2_2As2_2 displays conventional superconductivity, corroborating the substantial role of the 4ff electrons for the extraordinary superconducting state in CeRh2_2As2_2.

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