Continuum Schroedinger operators for sharply terminated graphene-like structures

We study the single electron model of a semi-infinite graphene sheet interfaced with the vacuum and terminated along a zigzag edge. The model is a Schroedinger operator acting on $L^2(\mathbb{R}^2)$: $H^λ_{\rm edge}=-Δ+λ^2 V_\sharp$, with a potential $V_\sharp$ given by a sum of translates an atomic potential well, $V_0$, of depth $λ^2$, centered on a subset of the vertices of a discrete honeycomb structure with a zigzag edge. We give a complete analysis of the low-lying energy spectrum of $H^λ_{\rm edge}$ in the strong binding regime ($λ$ large). In particular, we prove scaled resolvent convergence of $H^λ_{\rm edge}$ acting on $L^2(\mathbb{R}^2)$, to the (appropriately conjugated) resolvent of a limiting discrete tight-binding Hamiltonian acting in $l^2(\mathbb{N}_0;\mathbb{C}^2)$. We also prove the existence of {\it edge states}: solutions of the eigenvalue problem for $H^λ_{\rm edge}$ which are localized transverse to the edge and pseudo-periodic (propagating or plane-wave like) parallel to the edge. These edge states arise from a "flat-band" of eigenstates the tight-binding Hamiltonian.

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