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Complex magnetoelectric effect in PFN-PT/CoFe$_{2-x}$Zn$_x$O$_4$ bulk particulate composites

The structural, dielectric, magnetic, and magnetoelectric (ME) properties of particulate composites containing lead-iron niobate and lead titanate piezoelectric 0.94[PbFe$_{0.5}$Nb$_{0.5}$O$_3$]-0.06[PbTi$_{0.5}$O$_3$] (PFN-PT) and Zn-substituted cobalt ferrite magnetostrictive CoFe$_{2-x}$Zn$_{x}$O$_4$ (CF$_{2-x}$Z$_{x}$O); 0.6(PFN-PT)/0.4(CF$_{2-x}$Z$_{x}$O), x=0, 0.025, 0.1, 0.2, 0.3 (with ratio of 60 Wt\% ferroelectric and 40 Wt\% ferrite); have been investigated. We investigated the ME voltage coefficient as a complex quantity for all composite samples using the dynamic piezomagnetic coefficient, $q^{ac}$=$\partial λ^{ac}/{\partial H}$. The results reveal that tuning the magnetostrictive phase has a strong effect on the real part of the ME voltage coefficient. Doping zinc into cobalt ferrite modified the magnetic properties of the magnetic phase, such as magnetic anisotropy and coercive field, and hence the ME properties. The highest ME coefficient value of 12.33 $\frac{mV}{cm. Oe}$ was obtained for x=0.1 at the magnetic field of 755 Oe. In addition, the magnetic field at which the maximum value of the ME coefficient was observed ($H_{peak}$) strongly depends on the value of Zn substitution. The results were interpreted using the magnetic field dependence of the CF$_{2-x}$Z$_{x}$O magnetostriction.