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Comparison of mixed quantum states

In this article, we study the problem of comparing mixed quantum states: given $n$ unknown mixed quantum states, can one determine whether they are identical or not with an unambiguous quantum measurement? We first study universal comparison of mixed quantum states, and prove that this task is generally impossible to accomplish. Then, we focus on unambiguous comparison of $n$ mixed quantum states arbitrarily chosen from a set of $k$ mixed quantum states. The condition for the existence of an unambiguous measurement operator which can produce a conclusive result when the unknown states are actually the same and the condition for the existence of an unambiguous measurement operator when the unknown states are actually different are studied independently. We derive a necessary and sufficient condition for the existence of the first measurement operator, and a necessary condition and two sufficient conditions for the second. Furthermore, we find that the sufficiency of the necessary condition for the second measurement operator has simple and interesting dependence on $n$ and $k$. At the end, a unified condition is obtained for the simultaneous existence of these two unambiguous measurement operators.