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CO/H2, C/CO, OH/CO, and OH/O2 in Dense Interstellar Gas: From High Ionization to Low Metallicity

We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments include the cool interstellar medium (ISM) in low-metallicity dwarf galaxies, early enriched clouds at the reionization and Pop-II star formation era, and in dense cold gas exposed to intense X-ray or cosmic-ray sources. We focus on the behavior for H$_2$, CO, CH, OH, H$_2$O and O$_2$, at gas temperatures $\sim 100$ K, characteristic of a cooled ISM at low metallicities. We consider shielded or partially shielded one-zone gas parcels, and solve the gas phase chemical rate equations for the steady-state "metal-molecule" abundances for a wide range of ionization parameters, $ζ/n$, and metallicties, $Z'$. We find that the OH abundances are always maximal near the H-to-H$_2$ conversion points, and that large OH abundances persist at very low metallicities even when the hydrogen is predominantly atomic. We study the OH/O$_2$, C/CO and OH/CO abundance ratios, from large to small, as functions of $ζ/n$ and $Z'$. Much of the cold dense ISM for the Pop-II generation may have been OH-dominated and atomic rather than CO-dominated and molecular.