Cluster size distribution in the autocatalytic growth model

We generalize the model of transition-metal nanocluster growth in aqueous solution, proposed recently [Phys. Rev. E \textbf{87}, 022132 (2013)]. In order to model time evolution of the system, kinetic equations describing time dependence of the rate of chemical reactions are combined with Smoluchowski coagulation equation. In the absence of coagulation and fragmentation processes, the model equations are solved in two steps. First, for any injective functional dependence of the autocatalytic reaction rate constant on the cluster size, we obtain explicit analytical form of the $i$-mer concentration, $ξ_{i}$, as a function of $ξ_{1}$. This result allows us to reduce considerably the number of time-evolution equations. In the simplest situation, the remaining single kinetic equation for $ξ_{1}(t)$ is solved in quadratures. In a general case, we obtain small system of time-evolution equations, which, although rarely analytically tractable, can be relatively easily solved by using numerical methods.

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