Calculation of Effective Coulomb Interaction for Pr3+Pr^{3+}, U4+U^{4+}, and UPt3UPt_3

preprint1995arXivOpen access

Abstract

In this paper, the Slater integrals for a screened Coulomb interaction of the the Yukawa form are calculated and by fitting the Thomas-Fermi wavevector, good agreement is obtained with experiment for the multiplet spectra of Pr3+Pr^{3+} and U4+U^{4+} ions. Moreover, a predicted multiplet spectrum for the heavy fermion superconductor UPt3UPt_3 is shown with a calculated Coulomb U of 1.6 eV. These effective Coulomb interactions, which are quite simple to calculate, should be useful inputs to further many-body calculations in correlated electron metals.

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