Abstract
In this paper, we obtain a canonical factorization of basis elements in free Rota-Baxter algebras built on bracketed words. This canonical factorization is applied to give a coalgebra structure on the free Rota-Baxter algebras. Together with the Rota-Baxter algebra multiplication, this coproduct gives a bialgebra structure on the free Rota-Baxter algebra of rooted forests. When the weight of the Rota-Baxter algebra is zero, we further obtain a Hopf algebra structure.
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