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Anisotropic Stick-Slip Behavior of Aqueous Drops on Lubricated Chemically Heterogeneous Slippery Surfaces

Conventional slippery surfaces show isotropic drop mobility in all directions, but many applications require directional drop motion along a particular path only. In previous studies, researchers used topographic substrates, together with different external stimuli, to demonstrate anisotropic drop motion, which is not very efficient and cost-effective. Herein, we report a novel approach to smartly control drop motion on lubricating fluid coated chemically heterogeneous surfaces composed of alternating hydrophobic and hydrophilic stripes. Upon depositing an aqueous drop on such a surface, the underneath lubricating fluid dewets from the hydrophilic regions but remains intact on the hydrophobic ones, providing sticky and slippery areas for the drop. This results in remarkable anisotropic drop sliding behavior, from uniform motion along parallel to stripes to stick-slip motion along the perpendicular to them. Furthermore, we also demonstrate a phase diagram summarizing different dynamic situations exhibited by drops, sticking, or moving in one or both directions.