Abstract

The two-photon decay of heavy, helium-like ions is investigated based on second-order perturbation theory and Dirac's relativistic equation. Special attention has been paid to the angular emission of the two photons, i.e., how the angular correlation function depends on the shell structure of the ions in their initial and final states. Moreover, the effects from the (electric and magnetic) non-dipole terms in the expansion of the electron-photon interaction are discussed. Detailed calculations have been carried out for the two-photon decay of the 1s2s 1S01s2s \, ^1S_0, 1s2s 3S11s2s \, ^3S_1 and 1s2p 3P01s2p \, ^3P_0 states of helium-like xenon Xe52+^{52+}, gold Au77+^{77+} and uranium U90+^{90+} ions.

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