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Accuracy of Approximate Eigenstates

Besides perturbation theory, which requires, of course, the knowledge of the exact unperturbed solution, variational techniques represent the main tool for any investigation of the eigenvalue problem of some semibounded operator H in quantum theory. For a reasonable choice of the employed trial subspace of the domain of H, the lowest eigenvalues of H usually can be located with acceptable precision whereas the trial-subspace vectors corresponding to these eigenvalues approximate, in general, the exact eigenstates of H with much less accuracy. Accordingly, various measures for the accuracy of the approximate eigenstates derived by variational techniques are scrutinized. In particular, the matrix elements of the commutator of the operator H and (suitably chosen) different operators, with respect to degenerate approximate eigenstates of H obtained by some variational method, are proposed here as new criteria for the accuracy of variational eigenstates. These considerations are applied to that Hamiltonian the eigenvalue problem of which defines the "spinless Salpeter equation." This (bound-state) wave equation may be regarded as the most straightforward relativistic generalization of the usual nonrelativistic Schroedinger formalism, and is frequently used to describe, e.g., spin-averaged mass spectra of bound states of quarks.