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A New Star-Formation Rate Calibration from Polycyclic Aromatic Hydrocarbon Emission Features and Application to High Redshift Galaxies

We calibrate the integrated luminosity from the polycyclic aromatic hydrocarbon (PAH) features at 6.2\micron, 7.7\micron\ and 11.3\micron\ in galaxies as a measure of the star-formation rate (SFR). These features are strong (containing as much as 5-10\% of the total infrared luminosity) and suffer minimal extinction. Our calibration uses \spitzer\ Infrared Spectrograph (IRS) measurements of 105 galaxies at $0 < z < 0.4$, infrared (IR) luminosities of $10^9 - 10^{12} \lsol$, combined with other well-calibrated SFR indicators. The PAH luminosity correlates linearly with the SFR as measured by the extinction-corrected \ha\ luminosity over the range of luminosities in our calibration sample. The scatter is 0.14 dex comparable to that between SFRs derived from the \paa\ and extinction-corrected \ha\ emission lines, implying the PAH features may be as accurate a SFR indicator as hydrogen recombination lines. The PAH SFR relation depends on gas-phase metallicity, for which we supply an empirical correction for galaxies with $0.2 < \mathrm{Z} \lsim 0.7$~\zsol. We present a case study in advance of the \textit{James Webb Space Telescope} (\jwst), which will be capable of measuring SFRs from PAHs in distant galaxies at the peak of the SFR density in the universe ($z\sim2$) with SFRs as low as $\sim$~10~\sfrunits. We use \spitzer/IRS observations of the PAH features and \paa\ emission plus \ha\ measurements in lensed star-forming galaxies at $1 < z < 3$ to demonstrate the ability of the PAHs to derive accurate SFRs. We also demonstrate that because the PAH features dominate the mid-IR fluxes, broad-band mid-IR photometric measurements from \jwst\ will trace both the SFR and provide a way to exclude galaxies dominated by an AGN.