A generating integral for the matrix elements of the Coulomb Green's function with the Coulomb wave functions

preprint2020arXivOpen access

Abstract

We analytically evaluate the generating integral Knl(β,β′)=∫0∞∫0∞e−βr−β′r′Gnlrqr′q′drdr′K_{nl}(β,β') = \int_{0}^{\infty}\int_{0}^{\infty} e^{-βr - β' r'}G_{nl} r^{q} r'^{q'} dr dr' and integral moments Jnl(β,r)=∫0∞dr′Gnl(r,r′)r′qe−βr′J_{nl}(β, r) = \int_{0}^{\infty} dr' G_{nl}(r,r') r'^{q} e^{-βr'} for the reduced Coulomb Green's function Gnl(r,r′)G_{nl}(r,r') for all values of the parameters qq and q′q', when the integrals are convergent. These results can be used in second-order perturbation theory to analytically obtain the complete energy spectra and local physical characteristics such as electronic densities of multi-electron atoms or ions.

Explore this paper’s authors, topics and related work.

Building this map preview

BZPEER is loading the nearby papers, people, topics and institutions for this page.

Reviews 0

Write a reviewWrite

No reviews yet.

Discussion 0

Add a commentWrite

No comments yet.