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When studying thermalization of quantum systems, it is typical to ask whether a system interacting with an environment will evolve towards a local thermal state. Here, we show that a more general and relevant question is "when does a system thermalize relative to a particular reference?" By relative thermalization we mean that, as well as being in a local thermal state, the system is uncorrelated with the reference. We argue that this is necessary in order to apply standard statistical mechanics to the study of the interaction between a thermalized system and a reference. We then derive a condition for relative thermalization of quantum systems interacting with an arbitrary environment. This condition has two components: the first is state-independent, reflecting the structure of invariant subspaces, like energy shells, and the relative sizes of system and environment; the second depends on the initial correlations between reference, system and environment, measured in terms of conditional entropies. Intuitively, a small system interacting with a large environment is likely to thermalize relative to a reference, but only if, initially, the reference was not highly correlate
preprint / 2014